ABSTRACT
Zinc oxide (ZnO) nanoparticles are increasingly used in neutron fields, where zinc activation and copper buildup affect both safety and functional performance. This article
presents an isotope resolved modeling study of Zn(n,p)Cu activation in ZnO nanoparticles based on harmonized excitation functions for the 64Zn(n,p)64Cu,
66Zn(n,p)66Cu, 67Zn(n,p)67Cu and 68Zn(n,p)68Cu reactions. Cross sections calculated with the computer code are
mapped onto a common 0–20 MeV energy grid, folded with representative fast neutron spectra and coupled to Bateman inventory calculations for natural zinc in ZnO. The results
reveal a clear hierarchy, with 64Zn(n,p)64Cu dominating the fast spectrum response, 68Zn(n,p)68Cu providing a secondary contribution
and 66Zn(n,p)66Cu remaining minor. Despite its low cross section, 67Zn(n,p)67Cu generates medium lived 67Cu that governs
the residual copper inventory. The framework provides a compact basis for predicting activation in ZnO based components and for optimizing irradiation conditions for tailored
copper production.
Keywords: ZnO nanoparticles; zinc activation; Zn(n,p)Cu reactions; copper radionuclides.
DOI:10.70784/azip.1.2025424
Received: 17.11.2025
Internet publishing: 25.11.2025 AJP Fizika E 2025 04 en p.24-28
AUTHORS & AFFILIATIONS
Institute of Radiation Problems of Ministry of Science and Education AZ1143, B.Vahabzade 9, Baku, Azerbaijan
E-mail:
Graphics and Images
Fig.1-2-3-4
|
[1] Benjian Liu et al. "Enhanced performance of diamond Schottky nuclear batteries by using ZnO as electron transport layer" Diamond and Related Materials 109, 2020, 108026
[2] Xuan Lai et al. "ZnO NPs delay the recovery of psoriasis-like skin lesions through promoting nuclear translocation of p-NFκB p65 and cysteine deficiency in keratinocytes" Journal of Hazardous Materials 410, 2021, 124566
[3] Buse Ozen Ilik et al. "Elucidating the influences of Tantalum (V) oxide in Bi2O3–TeO2–ZnO ternary glasses: An experimental characterization study on optical and nuclear radiation transmission properties of high-density glasses" Ceramics International 49, 2023, 10906-10913
[4] R. El-Mallawany et al. "Optical properties and nuclear radiation shielding capacity of TeO2-Li2O-ZnO glasses" Optical Materials 106, 2020, 109988
[5] Y.S. Rammah et al. "Role of ZnO on TeO2.Li2O.ZnO glasses for optical and nuclear radiation shielding applications utilizing MCNP5 simulations and WINXCOM program" Journal of Non-Crystalline Solids 544, 2020, 120162
[6] A.S. Abouhaswa et al. "Nuclear shielding properties of B2O3–Pb3O4–ZnO glasses: Multiple impacts of Er2O3 additive" Ceramics International 46, 2020, 27849-27859
[7] M.I. Sayyed et al. "Tuning structural, optical, and radiation shielding properties of ZnO-enriched B2O3-Na2O-CaO-Y2O3-La2O3 borate glasses" Journal of Alloys and Compounds 1044, 2025, 184478
[8] M.Kh. Hamad. "Optical, photon interaction, and radiation shielding performance of Ho2O3-doped borate glasses modified with ZnO and CaO" Materials Research Bulletin 194, 2026, 113785
[9] M.H.A. Mhareb et al. "The correlation between optical, mechanical, and radiation shielding properties for SiO2–ZnO–PbO2 glass samples doped with different concentrations of Gd2O3" Radiation Physics and Chemistry 239, 2026, 113325
[10] M.I. Sayyed et al. "Revealing optical, mechanical and radiation shielding behavior of ZnO-PbO2-SiO2 Glasses" Chemical Physics Impact 11, 2025, 100949
[11] Flávio Henrique Covolam Boldrin et al. "The effect of calcination temperature on the performance of the CX/ZnO-CuxO in sulfamerazine photodegradation under solar and visible radiation" Optical Materials 168, 2025, 117404
[12] Elchin M. Huseynov, Anze Jazbec "Application of neutron transmutation technology to control the physical properties of nanoparticles at the atomic scale" Carbon 229, 119568, 2024
[13] Elchin M. Huseynov. "Modulation of conductivity in neutron-irradiated nanocrystalline β-SiC through trace and dopant elements" Journal of Electronic Materials 54, 2025, 8920–8934
[14] Elchin M. Huseynov. "FTIR spectroscopy of ZrC nanoparticles under the gamma radiation" Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 286, 122032, 2023
[15] Elchin M. Huseynov, Tural G. Naghiyev, Nijat R. Abbasov. "The paramagnetic approach of the color-changing of nano h-BN particle under the neutron irradiation" Physica E: Low-dimensional Systems and Nanostructures 139, 115124, 2022
[16] Elchin M. Huseynov, Tural G. Naghiyev. "Various thermal parameters investigation of 3C-SiC nanoparticles at the different heating rates" Applied Physics A 128, 115, 2022,
[17] Elchin M. Huseynov, Jale G. Atakishiyeva. "Characterizing neutron irradiation-induced effects in the nanocrystalline B4C particles using EPR spectroscopy" Solid State Sciences 154, 107604, 2024
[18] Elchin M. Huseynov, Tural G. Naghiyev. "Low temperature DSC investigation of neutron irradiated non-crystalline Si3N4 nanoparticles" Journal of Non-Crystalline Solids 647, 2025, 123272
[19] Abely E. Mwakuna et al. "ZnO-modified magnesium lead borate glasses: Optical, mechanical, and radiation shielding characteristics" Journal of Radiation Research and Applied Sciences 18, 2025, 101827
[20] M.I. Sayyed et al. "Enhancement of the radiation shielding properties of lead-borate glass: the impacts of Sb2O3, Al2O3 and ZnO" Radiation Physics and Chemistry 237, 2025, 113109
[21] Aljawhara H. Almuqrin et al. "Size matters: Radiation shielding superiority of borate glasses with nano vs. micro ZnO" Nuclear Engineering and Technology 57, 2025, 103614
[22] Olubusayo F. Oladejo et al. "Band engineering in ZnO/MoO3 heterojunction photodetector for improved photoelectrical response toward highly rated ultraviolet radiation sensing" Physica B: Condensed Matter 706, 2025, 417155
|